Comparative analysis of productive potential and fatty acid composition of oil from seeds of spring and winter turnip rape as perspective source for production of diesel biofuel compounds

  • R. Ya. Blume
  • G. V. Lantukh
  • A. I. Yemets
  • S. O. Rakhmetova
  • D. B. Rakhmetov
  • Ya. B. Blume

Abstract

Aim. Main aim of this research was a comparison of fatty acid composition for seed oils from of turnip rape breeding forms and varieties produced in M.M. Gryshko Natl. Botanical Garden of Natl. Academy of Sciences of Ukraine. Methods. Biochemical analysis of oil content as well as chromatographic analysis of fatty acid composition of mentioned above turnip rape genotypes were conducted out. Results. Oil content in seeds of spring (Brassica campestris f. annua D.C.) and winter (B. campestris f. biennis D.C.) turnip rape forms and varieties was determined. The highest oil content was indicated for winter variety Oriana – 38.1 %. Basing on chromatographic analysis indicated two types of fatty acid composition: high-erucic with content of 22:1 fatty acid up to 42.8 % and high-oleic with content of 18:1 fatty acid up to 46.92 %. Conclusions. Taking in account results of chromatographic analysis and agronomic productivity the best genotypes for biodiesel production were identified: winter variety Oriana and spring form EOSYaF-1. Chosen genotypes could be used for production of two different types of this biofuel – “light” and “heavy”, – according to difference in fatty acid composition.
Keywords: Brassicaceae, turnip rape, spring varieties, winter vatieties, oil, fatty acids, composition, biodiesel.

References

Atabani A.E., Silitonga A.S., Ong H.C., Mahlia T.M.I., Masjuki H.H., Badruddin I.A., Fayaz H. Non-edible vegetable oils: A critical evaluation of oil extraction, fatty acid compositions, biodiesel production, characteristics, engine performance and emissions production. Renew. Sustain. Energy Rev. 2013. V. 18. P. 211–245. doi: 10.1016/j.rser.2012.10.013

Balat M. Potential alternatives to edible oils for biodiesel production – A review of current work. Energy Convers. Manag. 2011. V. 52. P. 1479–1492. doi: 10.1016/j.enconman.2010.10.011

Wittkop B., Snowdon R.J., Friedt W. Status and perspectives of breeding for enhanced yield and quality of oilseed crops for Europe. Euphytica. 2009. V. 170. P. 131–140. doi: 10.1007/s10681-009-9940-5

Blium Ya.B., Hryhoriuk I.P., Dmytruk K.V., Dubrovin A.V., Iemets' A.I., Kaletnik H.M., Mel'nychuk M.D., Myronenko V.H., Rakhmetov D.B., Sybirnyy A.A., Tsyhankov S.P. Systema vykorystannia bioresursiv u novitnikh biotekhnolohiiakh otrymannia al'ternatyvnykh palyv. Kyiv: Ahrar Media Hrup, 2014. 359 s. [in Ukrainian]

Kushnir I.V. Perspektyvy rozvytku vyrobnytstva biodyzeliu v Ukraini. Zb. naukovykh prats' VNAU. Seriia: Ekonomichni nauky. 2011. No 1 (48). P. 41–45. [in Ukrainian]

Ratanapariyanuch K., Clancy J., Emami S., Cutler J., Reaney M.J.T. Physical, chemical, and lubricant properties of Brassicaceae oil. Eur. J. Lipid Sci. Technol. 2013. V. 115. P. 1005–1012. doi: 10.1002/ejlt.201200422

Rakhmetov D.B. Rol' novykh kul'tur u fitoenerhetytsi Ukrainy. Nauk. visn. NAU. 2007. No 116. P. 13–20. [in Ukrainian]

Rakhmetov D.B., Verhun O.M., Rakhmetova S.O., Pashyna O.O. Perspektyvy introduktsii ta selektsii vysokooliynykh maloposhyrenykh roslyn – iak dzherelo dlia biodyzelia. Mat-ly III mizhnar. nauk. konf-tsii. «Introduktsiia, selektsiia ta zakhyst roslyn». Donets'k. 2012. P. 104–105. [in Ukrainian]

Blume R.Ya., Boychuk Yu.M., Yemets A.I., Rakhmetova S.O., Blume Ya.B., Rakhmetov D.B. Porivnial'na otsinka zhyrnokyslotnoho skladu oliy nasinnia form ta sortiv tyfonu, red'ky oliynoi i ryzhiiu iak perspektyvnoi syrovyny dlia otrymannia biodyzeliu. Faktory eksperymental'noi evoliutsii orhanizmiv. 2016. V. 18. P. 61–66. [in Ukrainian]

Gumbyte M., Makarevičiene V., Kalenskaya S., Junik A. Aliejinguju augalu aliejaus panaudojimo galimybes biodyzelino gamybai. Zemes ukio Mokslai. 2013. V. 20 (1). P. 1–9. doi: 10.6001/zemesukiomokslai.v20i1.2633

Velasco L., Goffman F.D., Becker H.C. Variability for the fatty acid composition of the seed oil in a germplasm collection of the genus Brassica. Genet. Resources Crop Evol. 1998. V. 45. P. 371–382. doi: 10.1023/A:1008628624867

Barker G.C., Larson T.R., Graham I.A., Lynn J.R., King G.J. Novel insights into seed fatty acid synthesis and modification pathways from genetic diversity and quantitative trait loci analysis of the Brassica C genome. Plant Physiol. 2007. V. 144. P. 1827–1842. doi: 10.1104/pp.107.096172

Bereczky A., Torok A. International literature review on the possibilities of biodiesel production. Period. Polytech. Transp. Eng. 2011. V. 39 (1). P. 31–37. doi: 10.3311/pp.tr.2011-1.06

Kumar N., Varun, Chauhan S.R. Performance and emission characteristics of biodiesel from different origins: A review. Renew. Sust. Energy Rev. 2013. V. 21. P. 633–658. doi: 10.1016/j.rser.2013.01.006

Verma P., Sharma M.P. Performance and emission characteristics of biodiesel fuelled diesel engines. Int. J. Renew. Energy Res. 2015. V. 5 (1). P. 245–250.